Decorative laminates

ABSTRACT

Polyester resins are disclosed as the impregnant in the core sheets of heat and pressure consolidated laminates, especially decorative laminates having a core of a color complementing that of the decor sheet, and more especially those decorative laminates of unusual thickness.

BACKGROUND OF THE INVENTION

The production of high pressure, decorative laminates from thermosettingresin impregnated, cellulosic sheets is well known in the art. Theselaminates are generally manufactured from a core layer, a decorativelayer and optionally, an overlay layer. The core layer usually comprisesfrom 2-12 sheets of phenolic resin impregnated kraft paper, thedecorative layer usually comprises a melamine/formaldehyde resinimpregnated, α-cellulose-containing pigmented or printed paper sheet andthe overlay layer usually comprises a melamine-formaldehyde resinimpregnated, α-cellulose-containing paper sheet which is transparentwhen the three layers are heat and pressure consolidated into theultimate laminate. The thickness of these laminates normally ranges fromabout 1/16 inch to 3/8 inch although thicker higher pressure laminateshave been produced i.e. up to about 3/4-1 inch. Difficulties in themanufacture of such thick, high pressure, laminates, such as edgecrazing under ambient dry conditions or at high temperature, have,however, mitigated against the production thereof such that theselaminates constitute a very small percentage of the overall laminatemarket.

Attempts to produce thicker articles by gluing thin, high pressure,decorative laminates to one another have not proven successful becauseof the unattractive dark edge of the thin, laminates which isattributable to the phenolic resin in the core sheets and which istransferred to the thicker article. Additionally, the use of mostcommercially available adhesives to glue thin, high pressure, decorativelaminates to one another also imparts a distinct color to the edges ofthe thicker articles at the points where the thin, high pressure,decorative laminates are cemented together.

A recent development in the laminate industry has resulted in theproduction of thin, high pressure, decorative laminates having an edgecolor consistent with the color of the decorative sheet. This result isaccomplished by using pigmented kraft paper sheets in the core of thesame color as that of the pigmented decorative sheet. The phenolic resinin the core is replaced by a non-darkening resin thereby eliminating theundesirable dark edge, see U.S. Pat. No. 4,424,261 and pending U.S.application, Ser. No. 650,559 filed Sept. 13, 1984 now U.S. Pat. No.4,530,883, hereby incorporated herein by reference. The production ofthicker, high pressure, decorative laminates containing these newer,colored sheets also suffers from the same difficulties in production asthe thicker, darker edge, high pressure, decorative laminates i.e.incomplete curing of the resin, edge crazing, etc. Accordingly, if anarticle could be produced which does not have the tendency to craze atits edges upon subjection to high temperature and/or ambient dryness, astep forward in the art would be achieved.

SUMMARY OF THE INVENTION

It has now been found that thick articles which do not suffer from thedeficiencies normally connected with thick articles produced from anassembly of resin impregnated sheets (i.e. they are free from edgecrazing), can be produced by forming an assembly of polyester resinimpregnated core sheets and a melamine/formaldehyde thermosetting resinimpregnated decorative sheet, sufficient core sheets being used toachieve the desired thickness e.g. 1/32-11/2 inches. The assembly, whenheat and pressure consolidated, results in the formation of a thickarticle whose edge exhibits the color of the edges of the individualcore sheets from which the thick article is produced. If a plurality ofpigmented core sheets all of the same color, e.g. white, aresuperimposed atop a second plurality of pigmented core sheets of asecond color e.g. blue, the edge of the resultant thick article will bewhite and blue. A striped effect in the thick article can be achieved byutilizing many series of pluralities of different colored core sheets.It is indeed surprising that the polyester impregnated core sheets usedto produce the novel decorative articles of the present invention arecapable of bonding to the melamine/formaldehyde resin impregnated decorsheet because it was previously believed that such sheets would notconsolidate with other under the conditions of heat and pressure used toproduce such articles.

A further feature of the process of the present invention is the absenceof a need to cool the laminating press before the heat and pressureconsolidated laminate can be removed therefrom. Conventional laminateproduction requires that the press be cooled to about ambienttemperature under pressure in order that the properties of the resultantlaminate conform to the standards prescribed therefor. However, thelaminates of the present invention exhibit these desired properties ifthe press is opened hot and the laminate is removed immediately. Thus, asavings of time and energy is realized.

DESCRIPTION OF THE INVENTION INCLUDING PREFERRED EMBODIMENTS

The present invention is directed to a method for the production of adecorative article, especially one having a thickness ranging from about1/32 inch preferably 1/8 inch, to about 11/2 inches or more, whichcomprises forming a laminate assembly of, in superimposed relationship,a plurality of polyester resin impregnated paper core sheets and amelamine/formaldehyde resin impregnated decor sheet, wherein thepolyester resin has a molecular weight ranging from about 1-4 million,contains a peroxide catalyst and is colorless, and heat and pressureconsolidating the resultant assembly.

The present invention relates to decorative articles of manufacturecomprising (1) a core comprising a plurality of polyester resinimpregnated paper sheets and (2) a melamine-formaldehyde resinimpregnated decor sheet, wherein said polyester resin is as definedabove.

Any polyester resin conforming to the limitations expressed above may beused to impregnate the core sheets used to produce the novel articles ofthe present invention. These polyester resins are generally well knownin the art and are normally unsaturated polyesters produced from suchacids and anhydrides as isophthalic anhydride, oleic acid, adipic acid,maleic anhydride and the like, and such polyhydroxy alcohols as ethyleneglycol, propylene glycol, 1,3-propanediol, 1,2-butanediol,1,4-butanediol, glycerol, pinacol, 1,2-cyclopentanediol and the like.Such monomers as styrene, vinyl toluene, diallyl phthalate, vinylacetate, methyl methacrylate and the like may be used in conjuction withalcohols and acids or anhydrides mentioned above.

The polyester resin per se is colorless, but may be pigmented in anycolor, if desired. It contains a peroxide catalyst such as t-butylperbenzoate peroxide in order to assure complete curing thereof underthe conditions of heat and pressure consolidation. The molecular weightof the resin should range from about 1-4 million, preferably about 3million and is generally employed as a solution in any appropriatesolvent such as acetone.

The polyester resin is used to impregnate cellulosic paper sheets andthe sheets are then employed as the core in the production of theinstant decorative articles, the polyester resin replacing the phenolicresin conventionally used in the core sheets of such articles.

The core layer of such laminates is usually made up of a plurality ofpaper sheets, that is, 2-100, or more. The core sheets are usuallyconstructed of kraft paper, which can be extensible or non-extensible orused as a combination of such sheets. The kraft sheets can be unbleachedkraft, bleached kraft, pigmented kraft, pigmented bleached kraft, and soforth; sheets produced from other known pulp furnishings i.e. cotton,rayon etc. may also be used in the formation of articles in accordancewith the present invention.

The core sheets are preferably pigmented in a color so as to conform tothe color of the decorative sheet so that when the articles are cut ortrimmed to size, the edge appears of a color complementary to the colorof the articles' surface resulting from the decor sheet. A series ofpigmented core sheets of one color may also be positioned atop a secondseries of core sheets pigmented in a second color to thereby produce amulti-colored edged article. The properties of the resultant articlesmeet accepted and required NEMA and ISO standards and when exposed tohigh temperature or ambient dryness do not exhibit deleterious crazingon their edges. When exact matches to the surface color are required,the core sheets may be paper comprised of the same cellulosic furnishand pigments as the decor sheet and, as necessary, contain a high amountof alpha-cellulose.

The polyester resin may be used to impregnate the cellulosic paper coresheets of the decorative articles produced in accordance with thepresent invention in an amount ranging from about 25% to about 60%, byweight, based on the weight of the impregnated sheet, preferably, about30-45%.

Any melamine-formaldehyde resin known to be useful for the production ofdecorative laminates may be used to impregnate the decor sheet or sheetsof the laminates of the present invention. They are impregnated into thedecor sheets in standard amounts i.e. about 25-55%, by weight, based onthe weight of the impregnated sheet.

The novel decorative articles of the present invention range inthickness from about 1/32" to 11/2" or more and may be used as tops forvanities, counters, tables and the like.

The following examples are set forth for purposes of illustration onlyand are not to be construed as limitations on the present invention asset forth in the appended claims. All parts and percentages are byweight unless otherwise specified.

EXAMPLE 1

Three rolls of ninety-seven pound/3000 ft² basis weight bleached kraftpaper are each individually pigmented red, white and blue withappropriate pigments and saturated with a polyester resin produced from1 mole of isophthalic anhydride, 1 mole of maleic anhydride and 2.2moles of propylene glycol. The resin has a molecular weight of about 3-4million and contains t-butyl perbenzoate peroxide as a catalyst. Thepaper is impregnated to a 35% Rb resin level. The rolls are then driedand cut into 4'×10' sheets.

Thirty-two sheets of the white pigmented paper (as a mass) are thenplaced between thirty-three sheets of the red pigmented paper (as amass) and thirty-three sheets of the blue pigmented paper (as a mass). Asheet of blue pigmented alpha-cellulose paper which is impregnated withmelamine/formaldehyde resin is then placed atop the blue polyester resinimpregnated sheets and a sheet of red pigmented alpha-cellulose paperwhich is impregnated with the same melamine/formaldehyde resin is placedatop the red polyester resin impregnated sheets. The resultant assemblyis then heat and pressure consolidated at 140° C. for 30 minutes. Thepress is then allowed to cool to ambient temperature, opened and theresultant article recovered. The article is about 11/16" in thickness,blue on one side, red on the other and red, white and blue at its edges.

The article exhibits no edge crazing after 20 hours at 80° C.

EXAMPLE 2

The procedure of Example 1 is again followed except that the 33 sheetsof white, pigmented paper are reduced to 3 sheets, and each of the 33sheets of blue and red pigmented paper are eliminated. Themelamine/formaldehyde resin impregnated, alpha-cellulose sheets are bothwhite. The resultant laminate is about 1/32 inch in thickness andcompletely white throughout.

EXAMPLES 3-5

Again following the procedure of Example 1, excellent laminates areproduced when the polyester resin is replaced by the following polyesterresins:

(3) adipic acid/propylene glycol/styrene of 2.5 million molecularweight.

(4) isophthalic anhydride/ethylene glycol/propyleneglycol/methylmethacylate of 2-3 million molecular weight.

(5) Maleic anhydride/phthalic anhydride/1,4-butanediol/styrene having amolecular weight of 3.75 million.

EXAMPLE 6

The procedure of Example 1 is again followed except that the press isnot allowed to cool to ambient pressure before it is opened and thearticle recovered. Again, no edge crazing is exhibited by the articleafter 20 hours at 80° C. All other properties remain equivalent.

We claim:
 1. A heat and pressure consolidated laminate with superioredge crazing properties comprising:(1) a core comprising a plurality ofpolymerized polyester resin impregnated paper sheets, and, (2) one ormore polymerized melamine/formaldehyde resin impregnated decor outersheet(s) bonded theretowherein said core sheet(s) are impregnated with apolymerized colorless polyester resin .[.which has a molecular weightranging from about 1-4 million.]..
 2. A laminate according to claim 1wherein said decor sheet and said core sheets are pigmented in the samecolor.
 3. A laminate according to claim 1 wherein said core sheets arekraft paper sheets.
 4. A laminate according to claim 3 wherein all ofsaid core sheets are pigmented in the same color.
 5. A laminateaccording to claim 3 wherein said core sheets are pigmented in aplurality of colors.
 6. A laminate according to claim 1 wherein thepolyester resin prior to polymerization in the laminate is a copolymerof isophthalic anhydride, maleic anhydride and propylene glycol in moleratios of about 1:1 2.2, respectively.
 7. A laminate according to claim1 wherein the polyester resin prior to polymerization in the laminate isa copolymer of adipic acid, propylene glycol and styrene.
 8. A laminateaccording to claim 1 wherein the polyester resin prior to polymerizationin the laminate is a copolymer of maleic anhydride, phthalic anhydride,1,4-butanediol and styrene.
 9. A laminate according to claim 1 whereinthe polyester resin is impregnated into the core sheets in an amount offrom about 25% to 60% by weight thereof.